Phosphonate-substituted lignin as a flame retardant

ABSTRACT

Modified lignin having covalently attached phosphorous containing groups and methods for preparing such compounds are described herein. The modified lignin described herein provides a renewable source of flame retardant material.

CLAIM OF PRIORITY

This application is a U.S. national stage filing under 35 U.S.C. §371 ofInternational Application No. PCT/US2012/036291 filed May 3, 2012entitled “Phosphonate-Substituted Lignin As A Flame Retardant.”

SUMMARY

Various embodiments are directed to flame retardants including ligninand a phosphorous containing component covalently attached to thelignin. In some embodiments, the phosphorous containing component can betwo or more of phosphine, phosphine oxide, phosphinite, phosphonite,phosphinate, phosphonate, phosphate, or combinations thereof.

Other embodiments are directed to methods for producing flameretardants. Such methods generally include the steps of providing alignin having free hydroxyl groups in a solvent, contacting the ligninand a phosphorous containing compound to provide a reaction mixture, andintroducing a catalyst into the reaction mixture. In such embodiments,the lignin can react with the phosphorous containing compound to replaceone or more free hydroxyl groups on the lignin with a phosphorouscontaining compound to produce the flame retardant.

Further embodiments are directed to articles of manufacture includingflame retardants including a lignin and a phosphorous containingcomponent covalently attached to the lignin such as those describedabove.

BRIEF DESCRIPTION OF THE FIGURES

In the following detailed description, reference is made to theaccompanying drawings, which form a part hereof. In the drawings,similar symbols typically identify similar components unless contextdictates otherwise. The illustrative embodiments described in thedetailed description, drawings, and claims are not meant to be limiting.Other embodiments may be utilized and other changes may be made, withoutdeparting from the spirit or scope of the subject matter presentedherein. It will be readily understood that the aspects of the presentdisclosure, as generally described herein and illustrated in theFigures, can be arranged, substituted, combined, separated, and designedin a wide variety of different configurations, all of which areexplicitly contemplated herein.

FIG. 1. Generic structure of typical lignin substructure.

DETAILED DESCRIPTION

Lignin, FIG. 1, is a large natural polymer containing numerous aromaticmoieties and plentiful hydroxyl groups, extensively cross linked byether bonds. It is the second most abundant polymer on the planet aftercellulose and the most abundant non-petroleum source of aromaticcompounds. Lignin is found in the cell walls of all vascular plants andcan make up between 20% and 40% of the content of these plants and actsas a water transport system throughout the cell wall. Lignin also bondsplant cells together, giving plant stems rigidity and providing most ofthe material strength of the plant. Although lignin shows great promiseas a starting material for chemical synthesis, its heavily cross-linkednature makes it difficult to process. Therefore, lignin has historicallybeen either burned for energy or used as fillers in low margin, lowvalue niche applications. Hydroxyl groups (—OH) associated with lignincan serve as a pathway for attaching groups that change the propertiesof lignin, giving the material additional and desirable properties.

Like most organic materials, the oxygen-rich lignin burns when exposedto flame, and the addition of flame retardant additives has not allowedthese materials to meet fire retardant standards for residential orcommercial use. This invention proposes a novel flame retardant ligninhaving the unique chemistry of naturally occurring lignin that iscarefully manipulated to make it flame resistant. This material can beblended as filler into polymers, transferring the flame resistantproperties into those materials or electrospun into fibers for use asthermal insulation.

Embodiments of the invention are directed to modified lignin, methodsfor producing such modified lignin, and articles of manufactureincluding the modified lignin. The modified lignin of variousembodiments include, for example, introducing phosphorous containinggroups onto the lignin through free hydroxyl groups thereby augmentingthe inherit properties of lignin by making the lignin more flameresistant. The modified lignin provides a materially tough, cheap, andflame resistant material that can be used, for example, in thermalinsulation or as polymer additives. For example, the modified lignin ofembodiments can be incorporated into building insulation or used as afiller material in thermosets, thermoplastics, and rubbers and as areactant in the formation of epoxy-resins, polyurethanes,phenol-formaldehyde resins, and polyesters.

Lignin includes a variety of functional groups associated with thearomatic backbone (see, FIG. 1) including, for example, carboxylicacids, ketones, hydroxyls, and the like. In some embodiments, thesefunctional groups can be used to attach various pendant groups to thelignin. While embodiments are not limited to a particular type ofpendant group, in some embodiments, the pendant groups may include oneor more phosphorous atoms to provide lignin molecules having one or morephosphorous containing pendant groups. Any pendant group containing aphosphorous may be used in embodiments. For example, in someembodiments, the phosphorous containing component of a modified lignincan be a phosphine, phosphine oxide, phosphinite, phosphonite,phosphinate, phosphonate, phosphate, or combinations thereof. Suchphosphorous containing components can be substituted or unsubstitutedand when substituted can include any substituent including, for example,one or more C₁ to C₁₈ alkyl, C₂ to C₁₈ alkenyl, C₂ to C₁₈ alkynyl, C₅ toC₂₀ cycloalkyl, C₅ to C₂₀ aryl, or combinations thereof.

In particular embodiments, the phosphorous containing component mayinclude a compound of general formula:

where B can be a C₁ to C₁₈ alkyl, C₂ to C₁₈ alkenyl, C₂ to C₁₈ alkynyl,C₅ to C₂₀ cycloalkyl, or C₅ to C₂₀ aryl, each X can, independently, be aphosphorous containing substituent, and n is an integer of 2 to 8.

B is not limited, but in various embodiments is a cyclic, bicyclic,aromatic, heteroaromatic, poly-aromatic compound. For example, in someembodiments, B can be cyclopentyl, cyclohexyl, cyclooctyl, cyclodecyl,cyclopentyl-diene, benzyl, naphthyl, indenyl, or combinations thereof,and in certain embodiments, B can be benzyl. The B of the phosphorouscontaining component may include any number (n) of phosphorouscontaining substituents (X), and the number of substituents will varydepending on the number of carbon atoms in each B. For example, invarious embodiments, n can be 2, 3, 4, 5, 6, 7, or 8, and in furtherembodiments, in which B is a poly-aromatic compound n may be greaterthan 8. For example, n may be 9, 10, 11, 12, 14, or 16.

Each X in an individual phosphorous containing compound as presented inthe general formula above may be the same or different, and X can be anyphosphorous containing substituent known in the art. For example, insome embodiments, each X may, independently, be a phosphine, phosphineoxide, phosphinite, phosphonite, phosphinate, phosphonate, or phosphate.In addition, each X may, independently, include additional substituentsat one or more positions. “Substituent,” as used herein, refers to amolecular group that replaces a hydrogen in a hydrocarbon. The numberand type of substituents associated with X are not limited. In certainembodiments, substituents associated with X can include, but are notlimited to, trifluoromethyl, nitro, cyano, C₁-C₂₀ alkyl, aromatic oraryl, halide (F, Cl, Br, I), C₁-C₂₀ alkyl ether, C₁-C₂₀ alkyl ester,benzyl halide, benzyl ether, aromatic or aryl ether, hydroxy, alkoxy,amino, keto, alkylamino (—NHR′), dialkylamino (—NR′R″) or other groupsknown in the art. In the above examples, R′ and R″ can each,independently, be C₁ to C₁₈ alkyl, C₁ to C₁₈ alkoxy, C₂ to C₁₈ alkenyl,C₂ to C₁₈ alkynyl, C₅ to C₂₀ cycloalkyl, C₅ to C₂₀ aryl, C₅ to C₂₀aryloxy, and the like. In certain embodiments, X may be substituted withone or more C₁ to C₁₈ alkyl, C₁ to C₁₈ alkoxy, C₂ to C₁₈ alkenyl, C₂ toC₁₈ alkynyl, C₅ to C₂₀ cycloalkyl, C₅ to C₂₀ aryl, C₅ to C₂₀ aryloxy,and the like, which may or may not be further substituted with asubstituent such as those described above. For example, in someembodiments, one substituent associated with X may be an alkyl, alkoxy,aryl, or aryloxy group including one or more hydroxyl, halide, keto,amino, or other such substituent. In particular embodiments, X may bephosphonate and that is substituted at one or more carbon atoms withC₁-C₁₈ alkyl or C₁-C₁₈ alkoxy.

In further embodiments, the phosphorous containing component may be acompound of the general formula:

where X¹ and X² can, independently, be phosphine, phosphine oxide,phosphinite, phosphonite, phosphinate, phosphonate, or phosphate and m¹and m² are, independently, an integer of 1 to 10. In some embodiments,each of X¹ and X² may be independently substituted at one or morepositions with any of the substituents described above, and in certainembodiments, the substituent can, independently, be a C₁ to C₁₈ alkyl,C₂ to C₁₈ alkenyl, C₂ to C₁₈ alkynyl, C₅ to C₂₀ cycloalkyl, or C₅ to C₂₀aryl. In particular embodiments, X¹ and X² may each be phosphonate and,independently substituted within a C₁-C₁₈ alkyl. As such, in particularexemplary embodiments, the phosphorous containing component may be offormula:

Embodiments of the invention are not limited particularly to methylphosphonate as illustrated above. The methyl group may be replaced byany alkyl group.

In still other embodiments, B may be substituted at one or morepositions with a non-phosphorous containing substituent. For example, incertain embodiments, the B may include one or more substituentsincluding, but are not limited to, trifluoromethyl, nitro, cyano, C₁-C₂₀alkyl, aromatic or aryl, halide (F, Cl, Br, I), C₁-C₂₀ alkyl ether,C₁-C₂₀ alkyl ester, benzyl halide, benzyl ether, aromatic or aryl ether,hydroxy, alkoxy, amino, keto, alkylamino (—NHR'), dialkylamino (—NR′R″),or other groups known in the art.

The lignin used in various embodiments may be derived from any source,and the lignin can be a naturally occurring polymer, a syntheticallyproduced polymer, or a combination of these. For example, sources oflignin may include, but are not limited to, lignin sulfonates, Kraftlignins, soda lignins, organosolv lignins, softwood lignin, hardwoodlignin, cellulosic grasses lignins, corn stover lignins, steam explosionlignins, or combinations thereof. As indicated above, the functionalgroups present on the lignin may vary depending on, for example, thesource of the lignin. Certain functional groups may be more desirablethan others depending on the specific chemical modification used toobtain the flame retardant. For example, in particular embodiments, thelignin modified may include a large number of hydroxyl groups. Eachhydroxyl may be associated directly aromatic backbone, or in someembodiment, the hydroxyl may be associated with, for example, p-coumarylalcohol, coniferyl alcohol, sinapyl alcohol, and derivatives orcombinations thereof. The present invention is not limited to ligninobtained from specific sources.

A direct correlation can be made between the mass percentage ofphosphorus atoms in a molecule and the resulting fire resistance.Phosphorous containing compounds when combined with hydrocarbons andburned convert carbon/oxygen rich material to a non-flammable “char”layer that coats un-burnt material. This “char” cuts the fuel supply tothe flame, thereby inhibiting propagation of the flame and protectingthe underlying composition.

The lignin compounds described herein must generally include asufficient number of phosphorous containing components with sufficientregularity within the lignin to provide adequate “char.” Additionally,particular applications may require varying degrees of flame retardancy,which could reduce the amount of phosphorous containing componentnecessary for sufficient flame retardancy in those specificapplications. Therefore, the phosphorous content of the modified ligninof various embodiments may be about 0.1% to about 50% by weight of thelignin, or any value within this range, depending on the degree of flameretardancy required for a particular application. In some embodiments,the phosphorous content of the modified lignin embodied by the inventionmay be about 0.5 wt. % to about 40 wt. %, about 1 wt. % to about 35 wt.%, or about 5 wt. % to about 25 wt. %, or any value between theseranges. In still further embodiments, the phosphorous content of themodified lignin of the invention may be about 0.1 wt. %, about 0.5 wt.%, about 1 wt. %, about 5 wt. %, about 10 wt. %, about 15 wt. %, about20 wt. %, about 25 wt. %, about 30 wt. %, about 35 wt. %, about 40 wt.%, about 45 wt. %, about 50 wt. %, or any value there between.

Lignin modification can be performed by contacting or reacting a ligninwith a phosphorous containing component. The skilled artisan candetermine appropriate methods for preparing modified lignin such as themodified lignin described above, and the method used may vary dependingon the type of lignin modified, the functional groups present on thelignin, the type of phosphorous containing component introduced onto thelignin, and the extent to which the lignin is modified. In variousexemplary methods for preparing modified lignin, a lignin having freefunctional groups can be dissolved in an appropriate solvent and aphosphorous containing compound can be added to the solution to providea reaction mixture. In some embodiments, a catalyst can be introducedinto this reaction mixture.

During the reaction that occurs between the components of the reactionmixture, one or more free hydroxyl groups of the lignin are replacedwith the phosphorous containing compound as illustrated in the reactionscheme below:

The reaction scheme presented above shows an exemplary lignin 1 that isreacted with a phosphorous containing component precursor Z′ underconditions that allow the phosphorous containing component Z to becoupled to the lignin 1 through hydroxyls on the lignin 1 to produce amodified lignin 2. While the reaction scheme presented above shows thecoupling of the phosphorous containing component a hydroxyl groups, inother embodiments, the phosphorous containing component may be coupledto the lignin 1 at, for example, carboxylic acid, keto, or other oxygencontaining groups on the lignin 1.

Coupling can be carried out using any method known in the art. Forexample, in some embodiments, coupling between the phosphorouscontaining component Z and free hydroxyl groups on the lignin 1 canoccur via Mitsunobu coupling. In such embodiments, a catalyst capable ofinducing coupling of the phosphorous containing component and the lignin1 can be introduced into a reaction mixture including the lignin 1 and aphosphorous containing pre-cursor. Suitable catalyst in such embodimentsinclude, but are not limited to, triphenylphosphine, azopyridine,triphenylphosphine, diethyl azodicarboxylate, diisopropylazodicarboxylate, and various combinations thereof. Depending on thechoice of catalysts used, it may be possible to recover and recycle thecatalysts after the reaction, allowing them to be used for multiplecycles.

In some embodiments, the lignin 1 may be dissolved in a polar non-proticsolvent. The polar non-protic solvent is not limited. For example, invarious embodiments, polar non-protic solvents may include, but are notlimited to, dimethyl acetamide, nitromethane, acetonitrile,hexamethylphosphoramide, dimethylformamide, pyridine, 1,4-dioxane,N-methylpyrrolidone, sulfolane, 1-methyl-2-pyrolidianone, and the likeand combinations thereof. In particular embodiments, the solvent may bedimethyl sulfoxide which is known to be an excellent solvent for lignin1.

The phosphorous containing component precursor may vary amongembodiments. For example, in some embodiments, the phosphorouscontaining component precursor may include a phosphorous moiety such as,for example, a phosphine, phosphine oxide, phosphinite, phosphonite,phosphinate, phosphonate, phosphate, or combinations thereof covalentlyattached to one or more C₁ to C₁₈ alkyl, C₂ to C₁₈ alkenyl, C₂ to C₁₈alkynyl, C₅ to C₂₀ cycloalkyl, C₅ to C₂₀ aryl, or combinations thereof.In other embodiments, a phosphorous moiety such as those described abovecan include an additional moiety such as, for example, one or more C₁ toC₁₈ alkyl, C₂ to C₁₈ alkenyl, C₂ to C₁₈ alkynyl, C₅ to C₂₀ cycloalkyl,C₅ to C₂₀ aryl, or combinations thereof.

In particular embodiments, the phosphorous containing componentprecursor may be of general formula:(X

_(n)B—Ywhere B can be a C1 to C18 alkyl, C2 to C18 alkenyl, C2 to C18 alkynyl,C5 to C20 cycloalkyl, or C5 to C20 aryl, each X can, independently, bephosphine, phosphine oxide, phosphinite, phosphonite, phosphinate,phosphonate, or phosphate, n is an integer of 2 to 8, and Y is a leavinggroup. In some embodiments, B can be a cycloalkyl or aryl group such as,but not limited to, cyclopentyl, cyclohexyl, cyclooctyl, cyclodecyl,cyclopentyl-diene, benzyl, naphthyl, indenyl, or combinations thereof,and in certain embodiments, B can be benzyl. In further embodiments, Xcan be substituted at one or more positions with a substituent that can,independently, be C1 to C18 alkyl, C2 to C18 alkenyl, C2 to C18 alkynyl,C5 to C20 cycloalkyl, or C5 to C20 aryl. In some embodiments, n may be2, 3, or 4, and in particular embodiments, X may be phosphonatesubstituted with one or more C1-C18 alkyl. Y can be any leaving groupknown in the art. For example, Y may be hydroxyl, mesylate, tosylate,phosphite, ester, or cholorosulfite in various embodiments.

In certain embodiments, the phosphorous containing component precursormay be a compound of the general formula:

where each of X1 and X2 can, independently, be phosphine, phosphineoxide, phosphinite, phosphonite, phosphinate, phosphonate, or phosphate,m1 and m2 are, independently, an integer of 1 to 10, and Y is a leavinggroup. In some embodiments, each of X1 and X2 can independently, besubstituted at one or more positions with a substituent that can,independently, be C1 to C18 alkyl, C2 to C18 alkenyl, C2 to C18 alkynyl,C5 to C20 cycloalkyl, or C5 to C20 aryl. In particular embodiments, X1and X2 may each be phosphonate having one or more associated C1-C18alkyl groups. For example, in some embodiments, the phosphorouscontaining component precursor may be of the formula:

The amount of phosphorous containing component precursor included in thereaction mixture may vary among embodiments, and may depend, forexample, on the efficiency of the coupling reaction and the desireddegree of flame retardancy. In some embodiments, the phosphorouscontaining component precursor may be about 0.1% to about 50% by weightof the reaction mixture. In other embodiments, the amount of phosphorouscontaining component precursor in the reaction mixture may be about 0.5wt. % to about 40 wt. %, about 1 wt. % to about 35 wt. %, or about 5 wt.% to about 25 wt. %, or any value between these ranges. In still furtherembodiments, the amount of phosphorous containing component precursor inthe reaction mixture may be about 0.1 wt. %, about 0.5 wt. %, about 1wt. %, about 5 wt. %, about 10 wt. %, about 15 wt. %, about 20 wt. %,about 25 wt. %, about 30 wt. %, about 35 wt. %, about 40 wt. %, about 45wt. %, about 50 wt. %, or any value there between.

Following coupling the reaction may be terminated and the modifiedlignin 2 prepared may be purified away from the other components of thereaction mixture. Various methods for purifying lignin are known in theart and can be employed in embodiments of the invention. For example, insome embodiments, methods for preparing modified lignin 2 may includethe steps of precipitating the modified lignin 2 and collecting aprecipitated modified lignin 2. Precipitating may be carried out bycontacting the reaction mixture with a protic liquid, such as, forexample, water. Similarly, collecting the precipitate may be carried outby any method such as, for example, filtering the reaction mixture afterprecipitating, centrifugation of the precipitate lignin, heating toinduce evaporation of the solvent, or combinations thereof.

In further embodiments, methods for preparing modified lignin 2 mayinclude the steps of heating the precipitated modified lignin 2 in adilute base. The step of heating may be carried out for any amount oftime, but in certain embodiments, heating may be carried out for about 8hours to about 24 hours. There is no limit on the type of base. Forexample, in various embodiments, the dilute base may be sodiumhydroxide, potassium hydroxide, sodium bicarbonate, and the like, andthe concentration of the base in the dilute base solution may be about 1wt. % to about 5 wt. %, or any concentration between these values. Instill other embodiments, methods for preparing modified lignin 2 mayinclude neutralizing the pH of the precipitated modified lignin 2containing solution by adding an acid to the reaction mixture.Embodiments are not limited to particular acids. For example, in variousembodiments, neutralizing may be carried out by adding hydrochloric acid(HCl), sulfuric acid, nitric acid, or the like after the heating step.Generally, such acids can be at a concentration of 1 molar (M) or less,but any concentration can be used to effectuate neutralization.

In still further embodiments, methods for preparing modified lignin 2may include the step of dehydrating the precipitated modified lignin 2.Dehydrating can be carried out by any method and can include furtherheating to remove solvent and water or dehydrating at ambienttemperatures. In some embodiments, dehydrating may be carried out undervacuum.

Yet other embodiments may include the step of washing the precipitatedmodified lignin. Washing may be carried out at any time during thepurification process, and one or more washing steps can be includedeither as simultaneous washing steps or intermittent washing stepsbetween any of the steps of coupling, heating, neutralizing, ordehydrating as described above. Washing can be carried out using anysolvent including ethanol, methanol, acetone, and the like, or water. Incertain embodiments, simultaneous washing steps may be carried out withdifferent solvents and/or water.

Further methods embodied by the invention include preparing fibers fromthe modified lignin 2. Such fibers can be prepared using any method. Forexample, in some embodiments, fibers may be prepared by spinning thedehydrated modified lignin 2. In other embodiments, fibers may beprepared by dissolving the modified lignin 2 in a solvent and spinningthe modified lignin 2 into fibers. Such fibers may be used in numerousapplications, including, for example, as a flame retardant in fabricsand insulation.

In other embodiments, the modified lignin 2 may be incorporated intopolymers. For example, the modified lignin 2 may be incorporated intothermoset and thermoplastic engineering polymers such as, but notlimited to, polycarbonates, epoxies, polyepoxies, benzoxazines,polyacrylates, polyacrylonitriles, polyesters, such as, poly(ethyleneterephthalate), poly(trimethylene terephthalate), and poly(butyleneterephthalate), unsaturated polyesters, polyamides, polystyrenesincluding high impact strength polystyrene, polyureas, polyurethanes,polyphosphonates, polyphosphates, poly(acrylonitrile butadienestyrene)s, polyimides, polyarylates, poly(arylene ether)s,polyethylenes, polypropylenes, polyphenylene sulfides, poly(vinylester)s, polyvinyl chlorides, bismaleimide polymers, polyanhydrides,liquid crystalline polymers, cellulose polymers, and the like andcombinations thereof. The step of incorporating the modified lignin 2into a polymer may be carried out by any means. For example,incorporating may be carried out by compounding, mixing, blending, ormelt mixing the modified lignin 2 and the polymer.

In certain embodiments, the modified lignin 2 of the invention canundergo electrospinning to generate small fibers. In such embodiments,the modified lignin 2 can be dissolved in a solvent and spun into thethin fibers that can be incorporated into cloth, fabrics, fillermaterials for clothing, or insulation.

In particular embodiments, modified lignin 2 may be dissolved in anaprotic solvent such as dimethyl sulfoxide (DMSO) and contacted with aresin-bound triphenylphosphine/azopyridine. These modified Mitsunobuconditions avoid the traditional PPh₃/DEAD reagent set and allows foreasy recovery and recycling of the catalysts post reaction. A rapidMitsunobu coupling occurs, coupling the phosphorous containing componentto the lignin at free hydroxyl groups. In some embodiments, if lessflame retardancy is required, a stoichiometric amount of pyridine andthe desired number of equivalents of diethyl chlorophosphate can beadded to a DMSO solution of lignin. In such embodiments, a singlephosphate will be coupled to available hydroxyl groups. After coupling,the resulting lignin/DMSO mixture can be poured into water,precipitating the lignin as a white solid. The powder is collected byfiltration and heated in a dilute (1-5%) NaOH solution at 50-60° C.overnight, the pH is then neutralized with a mineral acid such as 1M HCl(aq). This generates modified lignin 2 that is flame retardant and hasthe necessary intramolecular attractions (hydrogen bonding between thelignin aldehydes/carboxylic acids and phosphoric acid) to provide the“stickiness” needed for fiber strength after electrospinning as well assuccessful blending into polymers as a flame-retardant filler.

The modified, flame-retardant lignin of various embodiments can beincorporated into numerous materials including, cloth, fabric, fillermaterials, and other flexible substrates. In other embodiments, themodified, flame-retardant lignin can be incorporated as a bulk powderinto thermoplastics or thermosets. For example, the modified lignin 2can be incorporated directing into epoxy resins or the modified lignin 2can be incorporated into mats or cloths used to prepare epoxy laminants.The modified lignin 2 can be used alone as a flame retardant filler orreinforcement material, or in still other embodiments, the modifiedlignin 2 can be combined with non-flame retardant lignin, other flameretardant additives, other fillers, or other reinforcement materials. Insuch embodiments, unmodified, non-flame retardant lignin can be blendedwith the modified lignin 2 to lower the concentration of phosphonategroups and reduce filler costs.

The modified lignin 2 described herein above may be incorporated into avariety of articles of manufacture. Such articles of manufacture mayinclude other fibers such as cotton, wool, polyester, or other commonlyused fibers that are used to produce, for example, fabrics that areincorporated into clothing, draperies, upholstery, and other sucharticles. In other embodiments, the articles of manufacture may includea polymer into which the modified lignin 2 is incorporated. As discussedabove, the polymer may be any thermoset or thermoplastic engineeringpolymer including, but are not limited to, polycarbonates, epoxies,derived polymers, polyepoxies, benzoxazines, polyacrylates,polyacrylonitriles, polyesters, such as, poly(ethylene terephthalate),poly(trimethylene terephthalate), and poly(butylene terephthalate),unsaturated polyesters, polyamides, polystyrenes including high impactstrength polystyrene, polyureas, polyurethanes, polyphosphonates,polyphosphates, poly(acrylonitrile butadiene styrene)s, polyimides,polyarylates, poly(arylene ether)s, polyethylenes, polypropylenes,polyphenylene sulfides, poly(vinyl ester)s, polyvinyl chlorides,bismaleimide polymers, polyanhydrides, liquid crystalline polymers,cellulose polymers, or combinations thereof. Examples of articles ofmanufacture encompassed by the invention include, but are not limitedto, coatings on plastics, metals, ceramic, or wood products,free-standing films, fibers, foams, molded articles, fiber reinforcedcomposites, support parts, electrical components, electrical connectors,printed wiring laminated boards, housings, subcomponents and components,televisions, computers, laptop computers, printers, cell phones, videogames, DVD players, and stereos.

Consumer electronics tend to produce significant heat and manufacturersare legally required to prepare articles of manufacture for electronicsused to be flame retardant or have some flame resistant properties.Thus, many electrical and electronic appliances are coated by flameretardant materials in order to avoid the possibility of fire in case ofa short-circuit or other similar failures in operation capable ofproducing a flame or a spark. As such, in certain embodiments, thepolymers and fibers including the modified lignin 2 of embodiments maybe used in electronics and electronic components.

EXAMPLE 1 Synthesis of the Phosphorous Containing Component

3,5-bis(bromomethyl)phenol can be protected with trimethylsilyl chloridethrough a well-known exchange reaction in which the trimethylsilyl groupis substituted for the hydrogen on phenol portion of the3,5-bisbromomethyl phenol. The3,5-bis(bromomethyl)phenoxy)trimethylsilane produced is then refluxedbriefly in neat trimethylphosphite to substitute a trimethylphosphitefor each bromide followed by Arbusov rearrangements to producetetramethyl(5-(trimethylsilyoxy)-1,3-phenylene)bis(methylene)diphosphonate. Thetrimethylsilane portion of the molecule is then removed by adding adilute acid such as dilute hydrochloric acid allowing mild hydrolysis toproduce the tetramethyl(5-hydroxy-1,3-phenylene)bis(methylene)diphosphonate phosphonatecontaining component that can be introduced onto lignin.

EXAMPLE 2 Modification of Lignin

An excess of the phosphorous containing component prepared in Example 1is dissolved in dimethyl sulfoxide (DMSO) and lignin is dissolved intothis mixture. Resin-bound triphenylphosphine and azopyridine are addedto this solution as catalysts. On addition of the catalysts, the freehydroxyl groups of the lignin are substituted by phosphorous containinggroups via Mitsunobu coupling, producing the flame retardant material.

Adding water to the resultant mixture stops the coupling reaction andprecipitates the material producing a white solid powder. This powder iscollected by filtration and heated in dilute sodium hydroxide (NaOH)solution (5%) at 50° C. for 12 hours. An appropriate quantity of 1 Mhydrochloric acid (HCl) is then added to neutralize the pH of themixture. The final dry flame retardant powder is then obtained bydehydrating the resulting suspension.

EXAMPLE 3 Flame Retardant Felt

The dry flame retardant powder produced in Example 2 can be combinedwith 20 mM and 400 mM ammonium chloride solutions which rehydrate thelignin powder and allow the lignin suspension to flocculate. Theflocculated lignin can then be extracted from the solution and washedwith water to remove residual ammonium chloride. The fibrous materialcan then be formed into a felt by spreading the wet material onto asheet and drying this sheet under heat. After drying a non-woven felt isformed that can be used to test flame retardancy.

A similar felt can be prepared using the same methodology with Kraftlignin powder purchased from a supplier that has not been modified toinclude the phosphorous containing component. Further felts can beproduced that include mixtures of modified and unmodified lignin inwhich the modified lignin is provided at 25 wt. %, 50 wt. %, and 75 wt.%. Still further felts can be produced that include cotton and wool orcotton/wool blends combined with the modified lignin in which themodified lignin is provided at 25 wt. %, 50 wt. %, and 75 wt. %.

Test articles can be manufactured from the felts described above andflame retardancy can be tested using the National Fire ProtectionAssociation (NFPA), titled NFPA 701: Standard Methods of Fire Tests forFlame Propagation of Textiles and Films, methods. Under NFPA 701, thefelt can be tested by burning a small sample and measuring the flame,char length, and flaming residue. The results of this testing shouldshow that the felt including only modified lignin shows excellent flameretardancy producing small flames and some smoldering, with minimalcharring, and leaving no flaming residue. In contrast, samples producedfrom unmodified lignin and cotton and cotton burn easily with heavycharring and flaming residue. Wool and cotton/wool blend materials burnless easily than the felt made with unmodified lignin and cotton, butburn, char, and produce some flaming residue. Flame retardancy should beimproved by incorporating modified lignin into materials includingunmodified lignin, cotton, wool, and cotton/wool blend material withfabrics meeting the NFPA 701 standards most likely being met at 50 wt. %or 75 wt. % modified lignin.

EXAMPLE 4 Flame Retardant Polymer

The dry flame retardant powder produced from Example 2 can beincorporated directly into a thermoplastic resin to improve flameretardancy of the polymer. Compositions can be produced that include 1wt. %, 2 wt. %, 5 wt. %, 10 wt. %, 20 wt. %, and 40 wt. % flameretardant powder by introducing the flame retardant powder into athermoplastic such as acrylonitrile butadiene styrene (ABS) andpolyamide (PA or Nylon) using an extruder that has been heated to anappropriate melting temperature or melt mixing the materials in a Thepolymer compositions produced can be removed from the extruder or mixerand molded into test articles.

Testing for flame retardancy can be carried out using the limitingoxygen index (LOI) or UL-94 standards. Compositions including themodified lignin should show improved flame retardancy over test articlesthat do not include modified lignin. An LOI of about 20 and a V-0 ratingwill most likely be achieved at 10 wt. % or 20 wt. % modified lignin forboth ABS and PA containing samples. Test articles can also be tested fornotched impact strength, tensile strength and so on. High concentrationsof modified lignin may negatively affect the toughness of the testsamples, but at concentration of less than 20 wt. % the toughness shouldnot be similar to samples including no lignin.

One skilled in the art will appreciate that, for this and otherprocesses and methods disclosed herein, the functions performed in theprocesses and methods may be implemented in differing order.Furthermore, the outlined steps and operations are only provided asexamples, and some of the steps and operations may be optional, combinedinto fewer steps and operations, or expanded into additional steps andoperations without detracting from the essence of the disclosedembodiments.

The present disclosure is not to be limited in terms of the particularembodiments described in this application, which are intended asillustrations of various aspects. Many modifications and variations canbe made without departing from its spirit and scope, as will be apparentto those skilled in the art. Functionally equivalent methods andapparatuses within the scope of the disclosure, in addition to thoseenumerated herein, will be apparent to those skilled in the art from theforegoing descriptions. Such modifications and variations are intendedto fall within the scope of the appended claims. The present disclosureis to be limited only by the terms of the appended claims, along withthe full scope of equivalents to which such claims are entitled. It isto be understood that this disclosure is not limited to particularmethods, reagents, compounds, compositions or biological systems, whichcan, of course, vary. It is also to be understood that the terminologyused herein is for the purpose of describing particular embodiments onlyand is not intended to be limiting.

With respect to the use of substantially any plural and/or singularterms herein, those having skill in the art can translate from theplural to the singular and/or from the singular to the plural as isappropriate to the context and/or application. The varioussingular/plural permutations may be expressly set forth herein for sakeof clarity.

It will be understood by those within the art that, in general, termsused herein, and especially in the appended claims (e.g., bodies of theappended claims) are generally intended as “open” terms (e.g., the term“including” should be interpreted as “including but not limited to,” theterm “having” should be interpreted as “having at least,” the term“includes” should be interpreted as “includes but is not limited to,”etc.). It will be further understood by those within the art that if aspecific number of an introduced claim recitation is intended, such anintent will be explicitly recited in the claim, and in the absence ofsuch recitation no such intent is present. For example, as an aid tounderstanding, the following appended claims may contain usage of theintroductory phrases “at least one” and “one or more” to introduce claimrecitations. However, the use of such phrases should not be construed toimply that the introduction of a claim recitation by the indefinitearticles “a” or “an” limits any particular claim containing suchintroduced claim recitation to embodiments containing only one suchrecitation, even when the same claim includes the introductory phrases“one or more” or “at least one” and indefinite articles such as “a” or“an” (e.g., “a” and/or “an” should be interpreted to mean “at least one”or “one or more”); the same holds true for the use of definite articlesused to introduce claim recitations. In addition, even if a specificnumber of an introduced claim recitation is explicitly recited, thoseskilled in the art will recognize that such recitation should beinterpreted to mean at least the recited number (e.g., the barerecitation of “two recitations,” without other modifiers, means at leasttwo recitations, or two or more recitations). Furthermore, in thoseinstances where a convention analogous to “at least one of A, B, and C,etc.” is used, in general such a construction is intended in the senseof one having skill in the art would understand the convention (e.g., “asystem having at least one of A, B, and C” would include but not belimited to systems that have A alone, B alone, C alone, A and Btogether, A and C together, B and C together, and/or A, B, and Ctogether, etc.). In those instances where a convention analogous to “atleast one of A, B, or C, etc.” is used, in general, such a constructionis intended in the sense of one having skill in the art would understandthe convention (e.g., “a system having at least one of A, B, or C” wouldinclude but not be limited to systems that have A alone, B alone, Calone, A and B together, A and C together, B and C together, and/or A,B, and C together, etc.). It will be further understood by those withinthe art that virtually any disjunctive word and/or phrase presenting twoor more alternative terms, whether in the description, claims, ordrawings, should be understood to contemplate the possibilities ofincluding one of the terms, either of the terms, or both terms. Forexample, the phrase “A or B” will be understood to include thepossibilities of “A” or “B” or “A and B.”

In addition, where features or aspects of the disclosure are describedin terms of Markush groups, those skilled in the art will recognize thatthe disclosure is also thereby described in terms of any individualmember or subgroup of members of the Markush group.

As will be understood by one skilled in the art, for any and allpurposes, such as in terms of providing a written description, allranges disclosed herein also encompass any and all possible subrangesand combinations of subranges thereof. Any listed range can be easilyrecognized as sufficiently describing and enabling the same range beingbroken down into at least equal halves, thirds, quarters, fifths,tenths, etc. As a non-limiting example, each range discussed herein canbe readily broken down into a lower third, middle third and upper third,etc. As will also be understood by one skilled in the art, all languagesuch as “up to,” “at least,” and the like include the number recited andrefer to ranges which can be subsequently broken down into subranges, asdiscussed above. Finally, as will be understood by one skilled in theart, a range includes each individual member. Thus, for example, a grouphaving 1-3 cells refers to groups having 1, 2, or 3 cells. Similarly, agroup having 1-5 cells refers to groups having 1, 2, 3, 4, or 5 cells,and so forth.

From the foregoing, it will be appreciated that various embodiments ofthe present disclosure have been described herein for purposes ofillustration, and that various modifications may be made withoutdeparting from the scope and spirit of the present disclosure.Accordingly, the various embodiments disclosed herein are not intendedto be limiting, with the true scope and spirit being indicated by thefollowing claims.

What is claimed is:
 1. A flame retardant comprising: a lignin covalentlybonded with a phosphorous containing component, the phosphorouscontaining component comprising a compound of general formula:

wherein: X¹ and X² are, phosphine, phosphine oxide, phosphinite,phosphonite, phosphinate, phosphonate, or phosphate; m¹ is an integer of1 to 10; and m² is an integer of 1 to
 10. 2. The flame retardant ofclaim 1, wherein each of X¹ and X² are independently substituted at oneor more positions with a substituent R, wherein R is independentlyselected from a group containing C₁ to C₁₈ alkyl, C₂ to C₁₈ alkenyl, C₂to C₁₈ alkynyl, C₅ to C₂₀ cycloalkyl, and C₅ to C₂₀ aryl.
 3. The flameretardant of claim 1, wherein the phosphorous containing componentcomprises:


4. The flame retardant of claim 1, wherein the phosphorous containingcomponent comprises about 0.1% to about 50% by weight to the flameretardant.
 5. The flame retardant of claim 1, wherein the lignincomprises lignin sulfonates, Kraft lignins, soda lignins, organosolvlignins, softwood lignin, hardwood lignin, cellulosic grasses lignins,corn stover lignins, steam explosion lignins, or combinations thereof.